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ISO 15901-2:2022
Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption — Part 2: Analysis of nanopores by gas adsorption- 발행일 : 2022-01-21
- 발행기관 : ISO
상세정보
분야 | ISO/TC 24/SC 4 : Particle characterization |
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적용범위 | This document describes a method for the evaluation of porosity and pore size distribution by physical adsorption (or physisorption). The method is limited to the determination of the quantity of a gas adsorbed per unit mass of sample as a function of pressure at a controlled, constant temperature[1]-[9]. Commonly used adsorptive gases for physical adsorption characterization include nitrogen, argon, krypton at the temperatures of liquid nitrogen and argon (77 K and 87 K respectively) as well as CO2 (at 273 K). Traditionally, nitrogen and argon adsorption at 77 K and 87 K, respectively, allows one to assess pores in the approximate range of widths 0,45 nm to 50 nm, although improvements in temperature control and pressure measurement allow larger pore widths to be evaluated. CO2 adsorption at 273 K – 293 K can be applied for the microporous carbon materials exhibiting ultramicropores. Krypton adsorption at 77 K and 87 K is used to determine the surface area or porosity of materials with small surface area or for the analysis of thin porous films. The method described is suitable for a wide range of porous materials. This document focuses on the determination of pore size distribution from as low as 0,4 nm up to approximately 100 nm. The determination of surface area is described in ISO 9277. The procedures which have been devised for the determination of the amount of gas adsorbed may be divided into two groups: — those which depend on the measurement of the amount of gas removed from the gas phase, i.e. manometric (volumetric) methods; — those which involve the measurement of the uptake of the gas by the adsorbent (i.e. direct determination of increase in mass by gravimetric methods). In practice, static or dynamic techniques can be used to determine the amount of gas adsorbed. However, the static manometric method is generally considered the most suitable technique for undertaking physisorption measurements with nitrogen, argon and krypton at cryogenic temperatures (i.e. 77 K and 87 K, the boiling temperature of nitrogen and argon, respectively) with the goal of obtaining pore volume and pore size information. This document focuses only on the application of the manometric method. |
국제분류(ICS)코드 | 19.120 : 입도 분석. 체가름 |
페이지수 | 29 |
Edition | 2 |
이력정보
No. | 표준번호 | 표준명 | 발행일 | 상태 |
---|---|---|---|---|
1 | ISO 15901-2:2022상세보기 | Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption — Part 2: Analysis of nanopores by gas adsorption | 2022-01-21 | 표준 |
2 | ISO 15901-2:2006/Cor 1:2007상세보기 | Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption — Part 2: Analysis of mesopores and macropores by gas adsorption — Technical Corrigendum 1 | 2007-05-07 | 구판 |
3 | ISO 15901-2:2006상세보기 | Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption — Part 2: Analysis of mesopores and macropores by gas adsorption | 2006-12-11 | 구판 |
관련상품
- ISO 15901-3:2007 - Pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption — Part 3: Analysis of micropores by gas adsorption
- ISO 15901-1:2016 - Evaluation of pore size distribution and porosity of solid materials by mercury porosimetry and gas adsorption — Part 1: Mercury porosimetry
다른 사람이 함께 구입한 상품
- ISO 9277:2022 - Determination of the specific surface area of solids by gas adsorption — BET method
- ISO 3923-1:2018 - Metallic powders — Determination of apparent density — Part 1: Funnel method
- KS A ISO 13320 - 입자 크기 분석 — 레이저 회절법
- KS C ISO 19749 - 나노기술 — 주사 전자현미경을 사용한 입자 크기 및 모양 분포 측정
- KS C IEC TS 62607-6-1 - 나노제조 — 주요 제어 특성 — 제6-1부: 그래핀-기반 물질 — 부피 비저항: 4-탐침 측정법
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